76235-03-5

Upstream product

• 7057-10-5 1,2-O-isopropylidene-α-D-5-deoxyglucurono-6,3-lactone 
• 76235-02-4 methyl 2,3-anhydro-5-O-benzyl-6-deoxy-α-D-allofuranoside 
• 76235-01-3 methyl 2-O-benzoyl-5-O-benzyl-3-chloro-3,6-dideoxy-α-D-glucofuranoside 
• 76234-94-1 methyl 2,3-di-O-acetyl-5-O-benzyl-6-deoxy-α-D-allofuranoside 
• 76234-91-8 methyl 5-O-benzyl-6-deoxy-α-D-allofuranoside 
• 76234-91-8 methyl 5-O-benzyl-6-deoxy-D-allofuranoside 
• 3067-56-9 (3aR,3bS,6aR,7aR)-6-Hydroxy-2,2-dimethyl-tetrahydro-furo[2',3':4,5]furo[2,3-d][1,3]dioxol-5-one 
• 111651-71-9 (4R,5S)-5-((R)-1-Benzyloxy-2,2-bis-ethylsulfanyl-ethyl)-4-hydroxy-dihydro-furan-2-one 
• 111651-72-0 (4R,5S)-5-((R)-1-Benzyloxy-2,2-bis-ethylsulfanyl-ethyl)-tetrahydro-furan-2,4-diol 
• 111651-70-8 (3aR,6R,6aS)-6-Benzyloxy-5-methoxy-tetrahydro-furo[3,2-b]furan-2-one 
• 111651-69-5 (3aR,6R,6aR)-6-Hydroxy-5-methoxy-tetrahydro-furo[3,2-b]furan-2-one 
• 57569-46-7 (3aR,3bR,6aS,7aR)-6-Chloro-2,2-dimethyl-tetrahydro-furo[2',3':4,5]furo[2,3-d][1,3]dioxol-5-one 
• 111651-73-1 (2S,3R)-2-((R)-1-Benzyloxy-2,2-bis-ethylsulfanyl-ethyl)-5-methoxy-tetrahydro-furan-3-ol 
• 119772-43-9 (3R,4R,5S)-5-Benzyloxy-1,1-dimethoxy-hexane-3,4-diol 

Downstream Products

• 76250-01-6 methyl varioside monobenzoate 
• 76235-04-6 methyl 5-O-benzyl-2,6-dideoxy-3-O-methyl-α-D-ribo-hexofuranoside 
• 78841-77-7 Methanesulfonic acid (2R,3R)-2-((S)-1-benzyloxy-ethyl)-5-methoxy-tetrahydro-furan-3-yl ester 

Relevant academic research and scientific papers

TOTAL SYNTHESIS OF METHYLFURANOSIDES OF 2-DEOXYPENTOSES AND 2,6-DIDEOXYHEXOSES. USE OF 1H AND 13C NMR SPECTROSCOPY TO DETERMINE THE STRUCTURE OF THE GLYCOSIDES OF 2-DEOXY SUGARS

The optimum results during the cyclization of the acyclic acetals of 2-deoxypentoses and 2,6-dideoxyhexoses are obtained when the reaction is conducted in a 0.01-0.05percent solution of hydrogen chloride in methanol at 20 deg C.Under these conditions cycl

Identification of Variose as 2,6-Dideoxy-3-O-methyl-D-ribo-hexose (D-Cymarose)

Variose, a sugar component of the antibiotic variamycin, has been identified as 2,6-dideoxy-3-O-methyl-D-ribo-hexose (i.e.D-cymarose).This assignment is based on the conversion of D-cymarose into, inter alia, methyl 2,6-dideoxy-3-O-methyl-α-D-ribo-hexofur