76263-88-2

Basic information

• Product Name: Phosphoric acid, diphenyl 1-phenylethyl ester
• CAS NO: 76263-88-2
• Molecular Formula: C20H19O4P
• Molecular Weight: 354.342
• Mol File: 76263-88-2.mol
• Article Data: 10

Chemical Properties

• CAS DataBase Reference: Phosphoric acid, diphenyl 1-phenylethyl ester(CAS DataBase Reference)
• NIST Chemistry Reference: Phosphoric acid, diphenyl 1-phenylethyl ester(76263-88-2)
• EPA Substance Registry System: Phosphoric acid, diphenyl 1-phenylethyl ester(76263-88-2)

Safety Data

• Hazardous Substances Data: 76263-88-2(Hazardous Substances Data)

Upstream product

• 2524-64-3 chlorophosphoric acid diphenyl ester 
• 2425-28-7 2-Bromo-1-phenylethanol 
• 98-85-1 1-Phenylethanol 

Downstream Products

• 143238-89-5 tert-butyl 2-methylene-4-phenylpentanoate 
• 93-96-9 bis(1-phenylethyl)ether 
• 94871-36-0 1,1,2-Triphenylpropane 
• 4769-42-0 9-(1-phenylethyl)-9H-fluorene 

Relevant articles and documents

Organocatalytic phosphorylation of alcohols using pyridine- N -oxide

Phosphorylation of alcohols by phosphoryl chlorides catalysed by pyridine-N-oxide is reported. The utility of this method is demonstrated through phosphorylation of primary, secondary and a tertiary alcohol as well as phenols under mild reaction conditions and with low catalyst loading (5 mol%).

Stereochemical consequences of the use of chiral N-phosphoryl oxazolidinones in the attempted kinetic resolution of bromomagnesium alkoxides

A number of chiral N-phosphoryl oxazolidinones have been prepared and evaluated as asymmetric phosphoryl transfer agents with the magnesium alkoxide of 1-phenyl ethanol. The reaction proceeded with little stereoselection, which was shown to be a consequence of the reaction mechanism that occurs with inversion of configuration at phosphorus consistent with in-line attack opposite the leaving group.

Design, synthesis, application and recovery of a minimally fluorous diaryl diselenide for the catalysis of stannane-mediated radical chain reactions

The synthesis of a minimally fluorous (52% F) diaryl diselenide is described. On reduction in situ with tributylstannane this diselenide provides a fluorous selenol which is effective in inhibiting a range of stannane-mediated radical rearrangements, including a cyclopropylcarbinyl ring opening. A method for the recovery of the fluorous diselenide involving continuous extraction in a modified, cooled continuous extractor is described.