76281-09-9Relevant academic research and scientific papers
KINETICS AND MECHANISM OF THE DOPING-ADDITION OF ArSCl TO OLEFINS
Kartashov, Viktor R.,Skorobogatova, E. V.,Grudzinskaja, E. Yu.,Akimkina, N. F.,Zefirov, Nikolai S.,Caple, R.
, p. 5219 - 5228 (2007/10/02)
A lithium perchlorate effect on the rate and product ratio of 2,4-dinitrobenzenesulfenyl chloride doping-addition to 1-methylcyclopropene (5) and tetrafluorobenzobarrelene (10) in acetic acid has been examined.The rates of both doping-addition reactions f
REACTION OF CYCLOPROPENE COMPOUNDS WITH BENZENESULFENYL CHLORIDES AND HYDROGEN CHLORIDE
Kartashov, V. R.,Skorobogatova, E. V.,Akimkina, N. F.,Zefirov, N. S.
, p. 32 - 35 (2007/10/02)
The reactions of 3,3-dimethylcyclopropene and 1-methylcyclopropene with 2,4-dinitrobenzene- and benzenesulfenyl chlorides and hydrogen chloride in acetic acid were investigated.It was shown that the reaction with benzenesulfenyl chlorides leads mainly to cyclic adducts, which are formed as a result of anti-addition of the reagent.Under the conditions of doping addition the predominant reaction path is the formation of the acyclic products.The addition of hydrogen chloride to the investigated hydrocarbons takes place entirely with ring opening.
