76372-95-7

Basic information

• Product Name: trans-2-diisopropylmethylsilyl-1-phenylethylene
• Synonyms: trans-2-diisopropylmethylsilyl-1-phenylethylene
• CAS NO: 76372-95-7
• Molecular Weight: 232.441
• Mol File: 76372-95-7.mol
• Article Data: 2

Chemical Properties

• CAS DataBase Reference: trans-2-diisopropylmethylsilyl-1-phenylethylene(CAS DataBase Reference)
• NIST Chemistry Reference: trans-2-diisopropylmethylsilyl-1-phenylethylene(76372-95-7)
• EPA Substance Registry System: trans-2-diisopropylmethylsilyl-1-phenylethylene(76372-95-7)

Safety Data

• Hazardous Substances Data: 76372-95-7(Hazardous Substances Data)

Upstream product

• 100-42-5 styrene 
• 18442-00-7 methyldiisopropylsilane 

Relevant articles and documents

The effect of solvents on hydrosilylation of phenylalkenes catalysed by 3>

Hydrosilylation of styrene, 2-phenyl-1-propene and trans-1-phenyl-1-propene by trialkylsilicon hydrides of the type CH3R2SiH (R = C2H5, i-C3H7, i-C4H9) catalysed by 3> in the presence of benzene, 1,3,5-triethylbenzene, 1,2,3,4-tetraethylbenzene, pentaethylbenzene, hexaethylbenzene, 1,2,3,4-tetrahydronaphthalene, cyclohexane, tetrahydrofuran (THF), tributylphosphate (TBP), dimethylacetamide (DMA), trimethylphosphate (TMP), tributylphosphate (TBP) and hexamethylphosphorictriamide (HMPA) has been studied both in anaerobic conditions and in the presence of air oxygen.Aromatic solvents were found to affect the composition of reaction products similarly as benzene.The use of THF, TBF, TMP, DMA and HMPA as solvents for hydrosilylation of styrene by the above silanes suppresses formation of the α-adduct when the reaction is carried out under unaerobic conditions.The yields of hydrosilylation of 2-phenyl-1-propene and trans-1-phenyl-1-propene by CH3(C2H5)2SiH are decreased by the addition of THF, TBP, TMP and DMA while they are increased by using HMPA as the solvent.