76395-12-5

Basic information

• Product Name: 1-Piperazinecarbothioic acid, S-methyl ester
• Synonyms: 1-Piperazinecarbothioic acid, S-methyl ester
• CAS NO: 76395-12-5
• Molecular Formula: C6H12N2OS
• Molecular Weight: 0
• Mol File: 76395-12-5.mol
• Article Data: 1

Chemical Properties

• Appearance: /
• CAS DataBase Reference: 1-Piperazinecarbothioic acid, S-methyl ester(CAS DataBase Reference)
• NIST Chemistry Reference: 1-Piperazinecarbothioic acid, S-methyl ester(76395-12-5)
• EPA Substance Registry System: 1-Piperazinecarbothioic acid, S-methyl ester(76395-12-5)

Safety Data

• Hazardous Substances Data: 76395-12-5(Hazardous Substances Data)

Upstream product

• 110-85-0 piperazine 
• 18369-83-0 methyl thiochloroformate 

Relevant articles and documents

Kinetics and mechanisms of the reactions of S-methyl chlorothioformate with pyridines and secondary alicyclic amines

The pyridinolysis of S-methyl chlorothioformate shows a biphasic Br?nsted-type plot, in agreement with a stepwise mechanism and a change in the rate-limiting step, from formation of a zwitterionic tetrahedral intermediate (T±) at high pKa to its breakdown at low pKa. The reaction of the same substrate with secondary alicyclic amines shows a linear Br?nsted-type plot of slope 0.23, which is in accordance with a stepwise mechanism where formation of T± is the rate-determining step for the whole pKa range examined.