76436-83-4Relevant academic research and scientific papers
A MECHANISM ON GENERATION AND RECYCLE OF THE SELENENYLATING REAGENTS IN ELECTROCHEMICAL OXYSELENENYLATION-DESELENENYLATION OF OLEFINS
Uneyama, Kenji,Ono, Michio,Torii, Sigeru
, p. 35 - 44 (2007/10/02)
The transformation of olefins 1 into allylic ethers and alcohols 2 (R = Me or H) was performed in 70-90percent yields, using a catalytic amount of diphenyl diselenide, by an electrochemical oxyselenenylation-deselenenylation sequence.The electrooxidation
A halide ion promoted electrochemical oxyselenenylation of olefins
Torii, Sigeru,Uneyama, Kenji,Ono, Michio
, p. 2741 - 2744 (2007/10/02)
A novel electrolytic transformation of olefins 1 into oxyselenides 2 has been performed in high yields and high regioselectivities by elctrolyzing olefins in protic solvents (MeOH, AcOH, H2O-MeCN) containing Et4NX (X = Cl, Br, I) and diphenyl diselenide using platinum foils.
