76449-67-7Relevant academic research and scientific papers
Trans dialkoxylation of cyclic alkenes: A Prevost-type reaction
Schauble, J. Herman,Trauffer, Edward A.,Deshpande, Prashant P.,Evans, Robert D.
, p. 1333 - 1339 (2005)
Reaction of anhydrous silver perchlorate, sym-collidine, and iodine (2:1:1 molar ratio) with cyclic alkenes and an excess of an alcohol in CH 2Cl2 affords trans-1,2-dialkoxycycloalkanes in high yields and purity. The reaction occurs via initial formation of the trans-iodoethers, which undergo Ag-assisted iodide abstraction to give the trans-diethers. Georg Thieme Verlag Stuttgart.
On the reaction of trisubstituted olefins with phenylselenenyl chloride in methanol
Ceccherelli,Curini,Marcotullio,Rosati
, p. 4211 - 4220 (2007/10/02)
The interaction of trisubstituted olefins with excess phenylselenenyl chloride in methanoi generates chloromethoxy dimethoxyderivatives. The mechanism of this transformation has been investigated.
Oxidation of Δ1-p-Menthene and Limonene with Thallium(III) Nitrate
Pol, A. V.,Naik, V. G.,Sonawane, H. R.
, p. 604 (2007/10/02)
The major reaction of Δ1-p-menthene with thallium(III) nitrate in methanol is found to be the solvolysis of C-Tl bond while the commonly observed oxidative rearrangement is the minor one.A new type of cyclization of limonene (2) to bicyclooctane system has been achieved for the first time in its reaction with TTN in methanol.A likely pathway of the cyclization reaction is proposed.
