76455-88-4

Basic information

• Product Name: C₁₄H₁₆N₂O₂S₂
• CAS NO: 76455-88-4
• Molecular Weight: 308.425
• Mol File: 76455-88-4.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: C₁₄H₁₆N₂O₂S₂(CAS DataBase Reference)
• NIST Chemistry Reference: C₁₄H₁₆N₂O₂S₂(76455-88-4)
• EPA Substance Registry System: C₁₄H₁₆N₂O₂S₂(76455-88-4)

Safety Data

• Hazardous Substances Data: 76455-88-4(Hazardous Substances Data)

Upstream product

• 19006-76-9 2-ethylthiopyridine 
• 127-65-1 chloroamine-T 
• 2637-34-5 2-Sulfanylpyridine 

Relevant articles and documents

Syntheses and Some Properties of Sulfoxides, Sulfilimines, Aminosulfonium Salts and Sulfoximines Containing Pyridine Nuclei

Several 2-pyridyl sulfides (1) (e.g., methyl (1a), ethyl (1b), isopropyl (1c), benzyl (1d), 1-phenylethyl (1e), l-menthyl (1f) 2-pyridyl sulfides); and bis(2-pyridylthio)methane (1g), and methyl 2-(N-oxy-pyridyl) sulfide (1h) were prepared by the usual method.Sulfoxides (2) were prepared by oxidation of the corresponding sulfides with m-chloroperbenzoic acid in good yields.A few sulfoxides were found to work as phase-transfer catalysts for some typical nucleophilic reactions in nonpolar solvents such as benzene, and in two-phase systems such as benzene-water.S-2-Pyridyl-N-(p-toluenesulfonyl) sulfinilimines (3) were prepared upon treatment of sulfides with Chloramine-T.Hydrolysis of N-(p-toluenesulfonyl)-2-pyridyl-o-tolylsulfilimine (3i) with conc. sulfuric acid gave the corresponding free sulfilimine in a moderate yield.S-2-Pyridyl sulfoximines (4) were not obtained by the general method from the sulfoxides and hydrazoic acid.Alkyl-2-pyridyl sulfoximines, however, were obtained by oxidation of the free sulfilimines derived from the corresponding aminosulfonium salts (5) prepared by reaction of the sulfides with mesitylene-sulfonylhydroxylamine (MSH).These free sulfilimines and sulfoximines thus prepared were found to give adducts with a few copper salts.