76465-28-6Relevant academic research and scientific papers
Preparation of Enamides via Reductive Acylation of N-Acetoxyimino Compounds by Use of Fe3(CO)12
Nakanishi, Saburo,Hirano, Takehiro,Otsuji, Yoshio,Itoh, Keiji
, p. 2167 - 2168 (2007/10/02)
Treatment of N-acetoxyimino compounds with Fe3(CO)12 in the presence of acyl halides and triethylamine gave enamides in good yields.
BECKMANN REARRANGEMENT OF α-SUBSTITUTED β-ARYL-α,β-UNSATURATED KETOXIMES IN PRESENCE OF PCl5
Zielinski, Wojciech
, p. 745 - 754 (2007/10/02)
The behavior of α-methylbenzylideneacetone and α-methylbenzylideneacetophenone oximes in presence of PCl5 under the Beckmann rearrangement conditions has been investigated.The possible formation of N-acyl-1-methyl-2-phenylvinylamines and other products, such as benzyl methyl ketone, unsubstituted amides or nitriles has been discussed.
