764651-36-7

Upstream product

• 896434-07-4 3-Methyl-butyric acid (1R,2R)-2-((R)-4-phenyl-2-thioxo-oxazolidine-3-carbonyl)-1-((S)-1-triethylsilanyloxy-ethyl)-hexyl ester 
• 100-51-6 benzyl alcohol 
• 142-61-0 Hexanoyl chloride 
• 896434-06-3 (R)-2-((1R,2S)-1-Hydroxy-2-triethylsilanyloxy-propyl)-1-((R)-4-phenyl-2-thioxo-oxazolidin-3-yl)-hexan-1-one 
• 896434-05-2 1-((R)-4-Phenyl-2-thioxo-oxazolidin-3-yl)-hexan-1-one 

Downstream Products

• 896434-08-5 (R)-2-[(1R,2S)-2-Hydroxy-1-(3-methyl-butyryloxy)-propyl]-hexanoic acid benzyl ester 
• 896434-09-6 (R)-2-[(1R,2S)-2-((2S,3R)-3-Benzyloxy-2-tert-butoxycarbonylamino-butyryloxy)-1-(3-methyl-butyryloxy)-propyl]-hexanoic acid benzyl ester 
• 896434-12-1 3-Methyl-butyric acid (2R,3S,6S,7R,8R)-3-(2-benzyloxy-3-formylamino-benzoylamino)-8-butyl-2,6-dimethyl-4,9-dioxo-[1,5]dioxonan-7-yl ester 
• 22083-60-9 antimycin A3 

Relevant academic research and scientific papers

Removal of thiazolidinethione auxiliaries with benzyl alcohol mediated by DMAP

In the presence of DMAP, a range of N-acylthiazaolidinethiones carrying different substituents were smoothly converted into the corresponding benzyl esters.

An expeditious enantioselective synthesis of antimycin A3b

A straightforward enantioselective route to (+)-antimycin A3b is presented, which used a TiCl4-mediated asymmetric aldolization to construct C-7/C-8 and BnOH/DMAP to remove the chiral auxiliary with concurrent protection of the carbo