76486-88-9Relevant articles and documents
Push-Pull Substituted Allenes, VI. Synthesis and Properties of 1,1-Diethoxy-3-acylallenes
Saalfrank, Rolf W.,Paul, Winfried,Schierling, Peter
, p. 3477 - 3487 (2007/10/02)
Reaction of the non enolizing 1,2-diketones 1 with (2,2-diethoxyvinylidene)triphenylphosphorane (2) yields the 1,1-diethoxy-3-acylallenes 4 via the remarkably stable oxaphosphetanes 3.With two exceptions these allenes dimerize spontaneously to form the po