7651-98-1

Upstream product

• 18281-78-2 S-propyl phosphorodichloridothioate 
• 20195-06-6 O,O-diethyl-S-n-propyl phosporothiolate 

Downstream Products

• 38528-21-1 Thiophosphoric acid O-(2-acetyl-phenyl) ester O'-ethyl ester S-propyl ester 
• 38528-17-5 4-(Ethoxy-propylsulfanyl-phosphoryloxy)-benzoic acid ethyl ester 
• 38528-02-8 Thiophosphoric acid O-(2-sec-butyl-phenyl) ester O'-ethyl ester S-propyl ester 
• 38524-59-3 O-ethyl-O-(3-methyl-4-methylmercaptophenyl)-S-n-propyl phosphorothiolate 
• 38524-85-5 Thiophosphoric acid O-(2,6-dichloro-4-nitro-phenyl) ester O'-ethyl ester S-propyl ester 
• 38527-99-0 Thiophosphoric acid O-ethyl ester O'-(2-isopropyl-phenyl) ester S-propyl ester 
• 38524-65-1 Thiophosphoric acid O-ethyl ester O'-(2-methyl-5-nitro-phenyl) ester S-propyl ester 
• 38524-44-6 Thiophosphoric acid O-(2,4-dibromo-phenyl) ester O'-ethyl ester S-propyl ester 
• 38524-84-4 Thiophosphoric acid O-(2,4-dichloro-6-methyl-phenyl) ester O'-ethyl ester S-propyl ester 
• 38524-80-0 phosphorothioic acid, O-(4-bromo-2,5-dichlorophenyl)-O-ethyl S-propylester 
• 38499-88-6 Thiophosphoric acid O-(2-bromo-phenyl) ester O'-ethyl ester S-propyl ester 
• 38524-54-8 Thiophosphoric acid O-(4-chloro-2-methyl-phenyl) ester O'-ethyl ester S-propyl ester 
• 38524-61-7 Thiophosphoric acid O-(2-chloro-4-nitro-phenyl) ester O'-ethyl ester S-propyl ester 
• 38524-64-0 Thiophosphoric acid O-ethyl ester O'-(4-methyl-3-nitro-phenyl) ester S-propyl ester 

Relevant academic research and scientific papers

The chlorination reaction of O-alkyl S-alkyl(aryl) thiophosphoric(-nic) acid derivatives with phosphorus oxychloride

It is reported that a variety of O-alkyl S-alkyl(aryl) thiophosphoric(-nic) acid derivatives 4 can be readily chlorinated with phosphorus oxychloride giving S-alkyl(aryl) thiophosphoro(-no)chloridates 2 and O-alkyl phosphorodichloridates 3.

Production of phosphoro chloride thiolates

A process for the production of a phosphoro chloride thiolate of the formula STR1 wherein R1 is alkyl, alkoxyalkyl, aryl, or aryl substituted by alkyl, alkoxy or halogen, and R2 is alkyl, comprising reacting a mixture of a dialkyl chlorophosphite of the formula and an alkyl dichloro-phosphite of the formula with a sulphenyl chloride of the formula to produce a mixture of a phosphorochloridothiolate of the formula STR2 and a phosphorodichloridothiolate of the formula STR3 and reacting the mixture without isolation with an alcohol of the formula in the presence of a dehydrochlorinating agent thereby to convert the phosphorodichloridothiolate of the formula STR4 to additional phosphorochloridothiolate STR5 The starting mixture is produced by reacting phosphorus trichloride with a trialkyl phosphite, or with an alcohol in the presence of a dehydrochlorinating agent.