76513-30-9Relevant academic research and scientific papers
Condensation of αβ-unsaturated amines with perfluoroarenes
Blazejewski, Jean-Claude,Wakselman, Claude
, p. 2845 - 2850 (2007/10/02)
Condensation of αβ-unsaturated amines (enamines, keten ON-acetals, ynamines) with perfluoroarenes (perfluorobenzene, perfluorotoluene, bromopentafluorobenzene, perfluoropyridine) leads to the formation of ketones, esters, and amines α-substituted by a perfluoroaryl group. In the case of enamines, C-arylation can be followed by intramolecular N-arylation, giving fluorinated tetrahydrocarbazoles which can then be dehydrogenated by chloranil to give fluorinated carbazoles.
