76527-29-2

Basic information

• Product Name: Oxiranecarboxylic acid, 3,3-dimethyl-2-phenyl-, methyl ester
• CAS NO: 76527-29-2
• Molecular Formula: C12H14O3
• Molecular Weight: 206.241
• Mol File: 76527-29-2.mol
• Article Data: 3

Chemical Properties

• CAS DataBase Reference: Oxiranecarboxylic acid, 3,3-dimethyl-2-phenyl-, methyl ester(CAS DataBase Reference)
• NIST Chemistry Reference: Oxiranecarboxylic acid, 3,3-dimethyl-2-phenyl-, methyl ester(76527-29-2)
• EPA Substance Registry System: Oxiranecarboxylic acid, 3,3-dimethyl-2-phenyl-, methyl ester(76527-29-2)

Safety Data

• Hazardous Substances Data: 76527-29-2(Hazardous Substances Data)

Upstream product

• 15206-55-0 methyl 2-oxo-2-phenylacetate 
• 152493-92-0 Methyl 2,2-dimethyl-3-phenyl-3-oxiranecarboximidate 
• 611-70-1 phenyl isopropyl ketone 
• 5445-32-9 2,2-Dimethyl-3-phenyl-3-oxiranecarbonitrile 
• 139616-15-2 C₁₂H₁₇O₅P 
• 67-64-1 acetone 
• 33131-36-1 methyl 3-methyl-2-phenylbut-2-enoate 

Relevant articles and documents

Electrolytic Oxidation of Ketones in a Methanolic Solution of NaCN in the Presence of Catalytic Amounts of KI

The indirect electrolytic oxidation of ketones (1) in methanolic sodium cyanide was studied using iodide ion as a mediator.The product and the reactivity of ketone were dependent on the nature of the alkyl groups attached to the carbonyl group.Thus, 2-alk

SYNTHESIS OF α,β-EPOXY DIAZOMETHYL KETONES

The preparation of eighteen epoxy diazomethyl ketones 1 is described.Two general methods were developed.Firstly, treatment of the mixed anhydrides of glycidic acids and carbonic acid ester with diazomethane led to the title compounds in yields ranging from 17-74 percent.Secondly, glycidyl chlorides which were obtained from sodium glycidates and oxalyl chloride, gave the desired products upon treatment with diazomethane ( yields 60-74 percent).The required α,β-epoxy carboxylic esters were prepared by Darzens condensation and epoxidation of α,β-unsaturated esters, but in some cases also by reaction of α-oxo carboxylic esters with diazomethane.