76527-29-2

Upstream product

• 33131-36-1 methyl 3-methyl-2-phenylbut-2-enoate 
• 139616-15-2 C₁₂H₁₇O₅P 
• 67-64-1 acetone 
• 152493-92-0 Methyl 2,2-dimethyl-3-phenyl-3-oxiranecarboximidate 
• 5445-32-9 2,2-Dimethyl-3-phenyl-3-oxiranecarbonitrile 
• 611-70-1 phenyl isopropyl ketone 
• 15206-55-0 methyl 2-oxo-2-phenylacetate 

Relevant academic research and scientific papers

Electrolytic Oxidation of Ketones in a Methanolic Solution of NaCN in the Presence of Catalytic Amounts of KI

The indirect electrolytic oxidation of ketones (1) in methanolic sodium cyanide was studied using iodide ion as a mediator.The product and the reactivity of ketone were dependent on the nature of the alkyl groups attached to the carbonyl group.Thus, 2-alk

Photochemical Wittig Reaction of Quasi-phosphonium Ylides

α-(Methoxycarbonyl)benzylidene quasi-phosphonium ylides, which are unreactive towards most carbonyl compounds, are found to undergo the Wittig reaction upon irradiation; irradiation with acyclic carbonyl compounds, e.g. benzaldehydes and acetophenones, af

SYNTHESIS OF α,β-EPOXY DIAZOMETHYL KETONES

The preparation of eighteen epoxy diazomethyl ketones 1 is described.Two general methods were developed.Firstly, treatment of the mixed anhydrides of glycidic acids and carbonic acid ester with diazomethane led to the title compounds in yields ranging from 17-74 percent.Secondly, glycidyl chlorides which were obtained from sodium glycidates and oxalyl chloride, gave the desired products upon treatment with diazomethane ( yields 60-74 percent).The required α,β-epoxy carboxylic esters were prepared by Darzens condensation and epoxidation of α,β-unsaturated esters, but in some cases also by reaction of α-oxo carboxylic esters with diazomethane.