7653-94-3

Basic information

• Product Name: 1-PHENYL-2,2-DIMETHYLCYCLOPROPANE
• Synonyms: 1-PHENYL-2,2-DIMETHYLCYCLOPROPANE
• CAS NO: 7653-94-3
• Molecular Formula: C₁₁H₁₄
• Molecular Weight: 146.23
• Mol File: 7653-94-3.mol
• Article Data: 17

Chemical Properties

• Boiling Point: 194.8°C at 760 mmHg
• Flash Point: 62.4°C
• Appearance: /
• Density: 0.938g/cm³
• Vapor Pressure: 0.607mmHg at 25°C
• Refractive Index: 1.522
• CAS DataBase Reference: 1-PHENYL-2,2-DIMETHYLCYCLOPROPANE(CAS DataBase Reference)
• NIST Chemistry Reference: 1-PHENYL-2,2-DIMETHYLCYCLOPROPANE(7653-94-3)
• EPA Substance Registry System: 1-PHENYL-2,2-DIMETHYLCYCLOPROPANE(7653-94-3)

Safety Data

• Statements: 10
• Safety Statements: 16
• RIDADR: 1993
• PackingGroup: II
• Hazardous Substances Data: 7653-94-3(Hazardous Substances Data)

Usage

Synthesis Reference(s)

Journal of the American Chemical Society, 99, p. 6097, 1977 DOI: 10.1021/ja00460a044Tetrahedron Letters, 24, p. 4591, 1983 DOI: 10.1016/S0040-4039(00)85964-X

InChI:InChI=1/C11H14/c1-11(2)8-10(11)9-6-4-3-5-7-9/h3-7,10H,8H2,1-2H3

Upstream product

• 186581-53-3 diazomethane 
• 611-69-8 rac-2-methyl-1-phenylpropan-1-ol 
• 56-23-5 tetrachloromethane 
• 768-49-0 (2-methyl-1-propenyl)-benzene 
• 51954-35-9 1,1-Diiod-2-phenylcyclopropan 
• 917-54-4 methyllithium 
• 3234-51-3 1,1-dibromo-2-phenylcyclopropane 
• 7087-58-3 2-phenyl-3,3-dimethyl-1,1-dichlorocyclopropane 
• 14389-04-9 tosylhydrazone of 2,2-dimethyl-3-phenylpropen-1-al 
• 100-42-5 styrene 
• 40852-89-9 i-propylidene diradical 
• 1865-29-8 2-phenyl-acrylic acid methyl ester 
• 79399-20-5 t-butyl (2-methyl-4-phenyl)but-2-yl sulphide 
• 79399-21-6 (2-methyl-4-phenylbutan-2-yl)(phenyl)sulfane 

Downstream Products

• 4489-84-3 3-methyl-1-phenylbut-2-ene 
• 6683-51-8 2-methyl-4-phenyl-1-butene 
• 43108-74-3 3-hydroxy-3-methyl-1-phenyl-1-butanone 
• 100532-42-1 (1,3-dimethoxy-3-methylbutyl)benzene 
• 104174-42-7 (±)-1-methyl-4-phenylbutane-2,4-diol 
• 97231-89-5 3-methoxy-3-methyl-1-phenylbutane 

Relevant articles and documents

Rhodium-Catalyzed Arylation of Cyclopropenes Based on Asymmetric Direct Functionalization of Three-Membered Carbocycles

A variety of highly diastereo- and enantiomerically enriched arylcyclopropanes is obtained through the asymmetric rhodium-catalyzed arylation reaction of achiral nonfunctionalized cyclopropene derivatives with commercially available aryl boronic acids in the presence of (R,S)-Josiphos.

Synergistic effect of additives on cyclopropanation of olefins

An efficient cyclopropanation of olefins with Zn(CH2I) 2, a catalytic amount of CCl3CO2H, and 1,2-dimethoxyethane at room temperature is described. A wide variety of olefins, including acid-sensitive substrates,

Oxovanadium(V)-induced oxidative ligand coupling of aryltrimethylzincates prepared from bromoarenes and dilithium tetramethylzincate

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