76532-83-7Relevant academic research and scientific papers
Synthesis of 3-fluoropyruvates from glycidic-α-cyanoesters
Chehidi,Chaabouni,Baklouti
, p. 237 - 241 (2007/10/03)
The decyanation of α-cyano-β-fluoro-α-hydroxyesters is achieved, at room temperature, by action of Ni(OAc)2. The corresponding 3-fluoropyruvates are obtained in good yields.
Fluorine-Containing Amino Acids and Their Derivatives. 3. Stereoselective Synthesis and Unusual Conformational Features of threo- and erythro-3-Fluorophenylalanine
Tsushima, Tadahiko,Kawada, Kenji,Nishikawa, Junko,Sato, Tomohiro,Tori, Kazuo,et al.
, p. 1163 - 1169 (2007/10/02)
Reductive amination of p-substituted 3-fluorophenylpyruvic acids gave p-substituted erythro-3-fluorophenylalanines with high stereoselectivity. threo-3-Fluorophenylalanine was prepared by enzymatic hydrolysis of the threo-3-fluorophenylalanine isopropyl e
3-Substituted-3-fluoropyruvic acids and their esters and salts, and production thereof
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, (2008/06/13)
A 3-substituted-3-fluoropyruvic acid and its ester and salt of the formula: STR1 wherein R is a lower alkyl group, a lower alkanoyl group, a fluorinated lower alkanoyl group, a substituted or unsubstituted phenyl group or a substituted or unsubstituted py
THE SYNTHESIS OF DERIVATIVES OF 3-FLUORO-2-KETOACIDS
Remli, M.,Ayi, A. I.,Guedj, R.
, p. 677 - 682 (2007/10/02)
3-Fluoro-2-hydroxynitriles Ia-h were found to be versatile intermediates to the 3-fluoropyruvic acids IIa-h via a new method for the synthesis of these important compounds.Treatment of IIa-h with diazomethane in anhydrous
α Fluorination of Ketones. 1. Direct Fluorination of Pyruvic Acid Derivatives by Using Molecular Fluorine
Tsushima, Tadahiko,Kawada, Kenji,Tsuji, Teruji,Misaki, Susumu
, p. 1107 - 1110 (2007/10/02)
Direct fluorination of enol-type 3-substituted pyruvates, e.g., those having aromatic and acyl substituents, by using molecular fluorine proceeds smoothly to produce a mixture of keto- and enol-type 3-substituted 3-fluoropyruvates in moderate to good yiel
Stereoselective synthesis of erythro-3-fluorophenylalanine
Tsushima, Tadahiko,Nishikawa, Junko,Sato, Tomohiro,Tanida, Hiroshi,Tori, Kazuo,Tsuji, Teruji,Misaki, Susumu,Suefuji, Masahiro
, p. 3593 - 3594 (2007/10/02)
Reductive amination of 3-fluorophenylpyruvic acid was found to give erythro-3-fluorophenylalanine with high selectivity.
