76617-38-4Relevant academic research and scientific papers
(PCy3)2Cl2Ru = CHPh Catalyzed Kharasch additions. Application in a formal olefin carbonylation
Lee, Belinda T.,Schrader, Thomas O.,Martín-Matute, Belén,Kauffman, Christopher R.,Zhang, Peng,Snapper, Marc L.
, p. 7391 - 7396 (2007/10/03)
(PCy3)2Cl2RuCHPh-catalyzed Kharasch additions of trihaloalkanes across olefins provide polyhalogenated adducts, which upon hydrolysis furnish α,β-unsaturated ketones, aldehydes, or γ-hydroxybutenolides. This two-step process represents an overall acylation or carbonylation of an olefin.
Oxidative addition of chloro- and dichloroacetic acid to alkenes to give α-chloro- and α,α-dichlorobutyrolactones with manganese(III) acetate
Snider, Barry B.,Che, Qinglin
, p. 325 - 332 (2007/10/03)
Oxidative addition of chloroacetic acid and dichloroacetic acid to alkenes with Mn(OAc)3 to give α-chloro- and α,α -dichlorobutyrolactones proceeds in moderate to good yield in MeCN containing one equivalent of the sodium salt of the carboxylic
