766546-98-9Relevant academic research and scientific papers
A biocatalytic route to enantioenriched, sulfanyl aldol products
Baker-Glenn,Ancliff,Gouverneur
, p. 7607 - 7619 (2007/10/03)
The aldol products derived from sulfur- or selenium containing acceptors were prepared by kinetic resolution in the presence of antibody 84G3 with enantiomeric excesses ranging from 56 to 70%. Much higher level of enantioselectivity was obtained (enantiomeric excesses all superior to 96%) for sulfanyl aldol products derived from thiomethoxyacetone with three different acceptors.
Total synthesis of leustroducsin B
Shimada, Kousei,Kaburagi, Yosuke,Fukuyama, Tohru
, p. 4048 - 4049 (2007/10/03)
A convergent total synthesis of leustroducsin B (1), which is known to exhibit a variety of biological activities, was successfully carried out. Notable features of our synthesis include construction of the C8 stereocenter by lipase-mediated desymmetrizat
