76679-45-3Relevant academic research and scientific papers
SYNTHESIS OF α- AND β-D-MANNOFURANOSIDES via 1-O-ALKYLATION
Schmidt, R. R.,Reichrath, M.,Moering, U.
, p. 3561 - 3564 (1980)
α- or, alternatively, β-glycoside and -disaccharide formation with 1-O-metalated mannofuranoses was performed via 1-O-alkylation with triflates.The high stereoselectivity observed is discussed in terms of intra- versus intermolecular complexation of the metal ion.
O-Alkylierung am anomeren Zentrum, 4. 1-O-Alkylierung von D-Mannofuranose und D-Mannopyranose
Schmidt, Richard R.,Moering, Ute,Reichrath, Manfred
, p. 39 - 49 (2007/10/02)
From 1-O-metallated 2,3;5,6-di-O-isopropylidene-D-mannose (1) and strong alkylating agents (triflates) β-D-mannofuranosides were obtained, addition of crown ether resulted in α-D-mannofuranoside formation.From the 6-O-unprotected D-mannose 7 a similar ste
