Tetrahedron Letters p. 3561 - 3564 (1980)
Update date:2022-08-16
Topics:
Schmidt, R. R.
Reichrath, M.
Moering, U.
α- or, alternatively, β-glycoside and -disaccharide formation with 1-O-metalated mannofuranoses was performed via 1-O-alkylation with triflates.The high stereoselectivity observed is discussed in terms of intra- versus intermolecular complexation of the metal ion.
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