SYNTHESIS OF α- AND β-D-MANNOFURANOSIDES via 1-O-ALKYLATION

DOI: 10.1016/0040-4039(80)80235-8

Source and publish data:

Tetrahedron Letters p. 3561 - 3564 (1980)

Update date:2022-08-16

Topics:

Authors:

Schmidt, R. R.

Reichrath, M.

Moering, U.

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Article abstract of DOI:10.1016/0040-4039(80)80235-8

α- or, alternatively, β-glycoside and -disaccharide formation with 1-O-metalated mannofuranoses was performed via 1-O-alkylation with triflates.The high stereoselectivity observed is discussed in terms of intra- versus intermolecular complexation of the metal ion.

Full text of DOI:10.1016/0040-4039(80)80235-8

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