76694-23-0Relevant academic research and scientific papers
Retention of Ring Configuration During Hydride Reduction of 4-Methoxycarbonyl-3,4-dihydro-1(2H)-isoquinolone Derivatives
Kansal, V. K.,Bhaduri, A. P.
, p. 1081 - 1082 (2007/10/02)
Retention of the ring configuration during the reduction of cis- and trans-methyl esters of 3-(o-anisyl)-4-carboxy-2-methyl-3,4-dihydro-1(2H)-isoquinolone with LiBH4 and LiAlH4 has been studied.It has been observed that the thermodynamic stability of the cis- and trans-isomers and their intermediates formed during the reaction influences the stereochemistry of the products obtained after reduction.
Carbon-13 NMR Studies: Effect of Steric Compression on Chemical Shifts of Carbon Atoms in the Heterocyclic Ring of Substituted 1,2,3,4-Tetrahydroisoquinolines
Kansal, V. K.,Bhaduri, A. P.
, p. 945 - 950 (2007/10/02)
Comparative 13C NMR spectra of 1,2,3,4-tetrasubstituted and 1,2-disubstituted 1,2,3,4-tetrahydroisoquinolines reveal the effect of steric compression on the chemical shifts of C-1, C-3 and C-4 carbon atoms in the heterocyclic ring of substituted 1,2,3,4-t
Acylation of Alcohols by Fatty Acid Esters in Presence of Lithium Aluminium Hydride
Kumar, Shiv,Kansal, V. K.,Prashad, Mahavir,Bhaduri, A. P.
, p. 856 - 858 (2007/10/02)
A novel acylation of alcohols by fatty acid esters in the presence of lithium aluminium hydride is reported.A plausible mechanism of this acylation through the formation of a lithium aluminium tetraalkoxide complex has been suggested.
