76705-02-7

Downstream Products

• 116232-59-8 trans-chlorophenyl(CO)platinum{dichlorophenylphosphino(cyclopentadienyl)2zirconium}2 
• 78064-22-9 [Pt2(μ-Cl)(μ-dppm)2(COPh)2]Cl 
• 60742-07-6 trans-benzoylchlorobis(methyldiphenylphosphine)platinum(II) 
• 74139-73-4 [PtCl(C₆H₅)(CO)(P(C₆H₄CH₃)3)] 
• 78064-11-6 [PtCl(COC₆H₅)((C₆H₅)2AsCH₂CH₂P(C₆H₅)2)] 
• 78147-54-3 [PtCl(C₆H₅)(CO)(P(C₆H₁₁)3)] 
• 78147-53-2 [Pt₂Cl₂(COC₆H₅)2(P(C₆H₁₁)3)2] 
• 78064-14-9 [PtCl(COC₆H₅)(P(C₆H₁₁)3)2] 
• 78064-20-7 [PtCl(COC₆H₅)(((C₆H₅)2PCH₂)2)] 
• 96806-48-3 [PtCl(COC₆H₅)(((C₆H₅)2PCH₂)2CH₂)] 
• 96806-49-4 [PtCl(COC₆H₅)((C₆H₅)2PCH₂CH₂SCH₃)] 
• 96806-50-7 [PtCl(COC₆H₅)((C₆H₅)2PCH₂CH₂N(CH₃)2)] 

Relevant academic research and scientific papers

Carbonylation of phenylplatinum(II) complexes containing bidentate ligands

A series of complexes of the type [PtClPh(P Y)] (P Y = 1,2-bis(diphenylphosphino)ethane (dppe), 1-(diphenylphosphino)-2-(diphenylarsino)ethane (appe), 1,3-bis(diphenylphosphino)propane (dppp), 1-(diphenylphosphino)-2-(methylthio)ethane (PC2S), or 1-(diphenylphosphino)-2-(dimethylamino)ethane (PC2N)) has been prepared and the carbonylation reactions of these complexes investigated. The corresponding benzoyl complexes have been generated by an alternative route. No reaction of [PtClPh(P Y)] with CO takes place when P Y = dppe or appe, but carbonylation proceeds smoothly, albeit slowly, when P Y = dppp, PC2S, or PC2N. The reaction is most rapid for the dppp complex. These results are rationalized in terms of both dissociative and nondissociative reaction pathways.

Reactivity of platinum diolefin complexes. Roles of trans influence and chelate effect

The complex [PtCl2(cod)] (cod = 1,5-cyclooctadiene) reacts with CO and tertiary phosphine to produce cis-[PtCl2(CO)L] (L = PEt3, P-n-Bu3, PMePh2, PPh3, P(C6H4F-p)