96806-49-4

Upstream product

• 96806-45-0 [PtCl(C₆H₅)((C₆H₅)2PCH₂CH₂SCH₃)] 
• 76705-02-7 chlorophenyl(CO)platinum(cod) 
• 20859-51-2 1-(methylthio)-2-(diphenylphosphino)ethane 

Downstream Products

• 92763-60-5 dichloro(1-methylthio-2-(diphenylphosphino)ethane)platinum(II) 
• 96806-45-0 [PtCl(C₆H₅)((C₆H₅)2PCH₂CH₂SCH₃)] 

Relevant academic research and scientific papers

Carbonylation of phenylplatinum(II) complexes containing bidentate ligands

A series of complexes of the type [PtClPh(P Y)] (P Y = 1,2-bis(diphenylphosphino)ethane (dppe), 1-(diphenylphosphino)-2-(diphenylarsino)ethane (appe), 1,3-bis(diphenylphosphino)propane (dppp), 1-(diphenylphosphino)-2-(methylthio)ethane (PC2S), or 1-(diphenylphosphino)-2-(dimethylamino)ethane (PC2N)) has been prepared and the carbonylation reactions of these complexes investigated. The corresponding benzoyl complexes have been generated by an alternative route. No reaction of [PtClPh(P Y)] with CO takes place when P Y = dppe or appe, but carbonylation proceeds smoothly, albeit slowly, when P Y = dppp, PC2S, or PC2N. The reaction is most rapid for the dppp complex. These results are rationalized in terms of both dissociative and nondissociative reaction pathways.