767319-64-2

Upstream product

• 767319-38-0 (-)-(1Z,2S,3R,4S)-1-ethylidene-2,4-dimethyl-5-oxo-3-((1S)-1-phenylethoxy)-heptyl isobutyrate 
• 767319-44-8 (-)-(2S,3S,4S,5S,6S)-3-ethyl-3-hydroxy-2,4,6-trimethyl-5-((1S)-1-phenylethoxy)cyclohexan-1-one 
• 123163-88-2 (1RS,4SR,5RS,6RS)-5-endo-chloro-6-exo-benzenesulfenyl-7-oxa-2-bicyclo<2.2.1>heptanone 

Relevant academic research and scientific papers

Synthesis of the cyclohexan subunit of baconipyrones A and B from furan.

[figure: see text] The synthesis of the cyclohexan subunit of the siphonarlid metabolites baconipyrones A and B from furan is described. A key step included the alkylative ring opening of 7-oxanorbornenic sulfone 4 and oxidative desulfonylation of compoun

On the Origin of Dolabriferol: Total Synthesis via Its Putative Contiguous Precursor

The putative contiguous polypropionate precursor of dolabriferol was synthesized using as the key step a rationally designed enantiomer-selective aldol coupling (i.e., with kinetic resolution) of a racemic C1-C8 ketone fragment with an enantiopure C9-C15

Total synthesis of polypropionate natural products: Application of new sulfur dioxide chemistry

In the presence of a Lewis or protic acid at low temperature, electron-rich dienes add to sulfur dioxide and carbon nucleophiles generating silyl sulfinates. The latter can be transformed into valuable polyketide precursors. Copyright Taylor & Francis Inc

First asymmetric synthesis of the cyclohexanone subunit of baconipyrones A and B. Revision of its structure

(Chemical Equation Presented) An asymmetric synthesis of the 3,5-dihydroxycyclohexanone subunit of baconipyrones A and B, as well as that of the hydroxydiketone subunit of baconipyrones C and D ((-)-(4S,6S)-4,6-dimethyl- 5-hydroxynonan-3,7-dione), is desc