767340-75-0

Upstream product

• 20672-67-7 methyl 3,4,6-tri-O-benzyl-α-D-mannopyranoside 
• 613243-01-9 {(E)-3-[diethylamino(dimethylsilyl)]allyl}trimethylsilane 
• 20672-69-9 methyl 2-O-acetyl-3,4,6-tri-O-benzyl-α-D-mannopyranoside 
• 29073-91-4 1,2-O-(1-methoxyethylidene)-β-D-mannopyranose 
• 68681-00-5 3,4,6-tri-O-benzyl-1,2-O-<1-(R)-methoxyethylidene>-β-D-mannopyranose 
• 3254-16-8 3,4,6-tri-O-acetyl-1,2-O-(1-methoxyethylidene)-β-D-mannopyranose 
• 767340-68-1 methyl 2-O-allyl(dimethyl)silanyl-3,4,6-tri-O-benzyl-α-D-mannopyranoside 

Relevant academic research and scientific papers

Stereoselective synthesis of allyl-C-mannosyl compounds: Use of a temporary silicon connection in intramolecular allylation strategies with allylsilanes

Methyl mannoside 16 containing an allyldimethylsilyl ether at C(2) was synthesized in nine steps from D-mannose. Reaction with TMSOTf in MeCN at room-temperature effected C-glycosylation to provide the α-allyl-C- mannosyl product 18 with excellent stereos