76740-66-4Relevant academic research and scientific papers
Structural and mechanistic studies of coordination compounds. 27. Synthesis and characterization of some trans ruthenium(III) complexes with four different saturated macrocyclic quadridentate secondary amines
Poon, Chung-Kwong,Che, Chi-Ming
, p. 1640 - 1643 (1981)
Some ruthenium(III) complexes of the type trans-[Ru(L)X2]+ with four different saturated macrocyclic quadridentate secondary amines [L = 1,4,8,11-tetraazacyclotetradecane (cyclam), X2 = (Cl)Br, I2, (NCS)2, and (CH3COO)2; L = 1,4,8,12-tetraazacyclopentadecane ([15]aneN4), C-meso- and C-rac-5,5,7,12,12,14-hexamethyl-1,4,8,11-tetraazacyclotetradecane (teta and tetb respectively), X2 = Cl2 and Br2] have been prepared and characterized. They are all monomeric, low-spin species with a trans configuration. The electronic and infrared absorption spectra of these complexes are discussed.
