76763-85-4Relevant academic research and scientific papers
REMOTE SUBSTITUENT EFFECTS IN THE BAEYER-VILLIGER OXIDATION. II. REGIOSELECTION BASED ON THE HYDROXYL GROUP ORIENTATION IN THE TETRAHEDRAL INTERMEDIATE
Noyori, R.,Kobayashi, H.,Sato, T.
, p. 2573 - 2576 (1980)
A remote directing effect in the Baeyer-Villiger oxidation of 8-oxabicyclo-octan-3-one derivatives has been interpreted in terms of chiral orientation of the hydroxyl nonbonding electron pairs in the tetrahedral intermediates.
