REMOTE SUBSTITUENT EFFECTS IN THE BAEYER-VILLIGER OXIDATION. II. REGIOSELECTION BASED ON THE HYDROXYL GROUP ORIENTATION IN THE TETRAHEDRAL INTERMEDIATE

DOI: 10.1016/0040-4039(80)80133-X

Source and publish data:

Tetrahedron Letters p. 2573 - 2576 (1980)

Update date:2022-08-02

Topics:

Authors:

Noyori, R.

Kobayashi, H.

Sato, T.

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Article abstract of DOI:10.1016/0040-4039(80)80133-X

A remote directing effect in the Baeyer-Villiger oxidation of 8-oxabicyclo<3.2.1>-octan-3-one derivatives has been interpreted in terms of chiral orientation of the hydroxyl nonbonding electron pairs in the tetrahedral intermediates.

Full text of DOI:10.1016/0040-4039(80)80133-X

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