76782-19-9Relevant articles and documents
Preparative synthesis of ethyl 5-acyl-4-pyrone-2-carboxylates and 6-aryl-, 6-alkyl-, and 5-acylcomanic acids on their basis
Obydennov,Goncharov,Sosnovskikh, V. Ya.
, p. 2233 - 2242 (2017/05/12)
A simple and efficient method for the synthesis of ethyl 5-alkanoyl- and 5-aroyl-4-pyrone-2-carboxylates was developed, which is based on the condensation of 1-R-2-(dimethyl-aminomethylidene)butane-1,3-diones, obtained from 1,3-diketones and dimethylforma
Synthesis of 6-aryl- and 5-aroylcomanic acids from 5-aroyl-2-carbethoxy-4- pyrones via a deformylative rearrangement and ring-opening/ring-closure sequence
Obydennov, Dmitrii L.,R?schenthaler, Gerd-Volker,Sosnovskikh, Vyacheslav Ya.
, p. 472 - 474 (2014/01/06)
The reaction of 1-aryl-2-(dimethylaminomethylene)butane-1,3-diones with diethyl oxalate in the presence of sodium hydride in THF gave ethyl 5-aroyl-4-oxo-4H-pyran-2-carboxylates, from which 4-oxo-6-aryl-4H-pyran-2- carboxylic acids (6-arylcomanic acids) w
THE SYNTHESIS AND REARRANGEMENT OF EPOXYPYRONES
Ross, William J.,Todd, Alec,Clark, Barry P.,Morgan, Sarah E.,Baldwin, Jack E.
, p. 2207 - 2208 (2007/10/02)
The oxidation of 5-acyl-4-oxo-pyran-2-carboxylic acid esters 1,2 to novel epoxypyrones and subsequent rearrangement to the previously inaccesible 6-substituted-5-hydroxy or 5-chloropyrones 6 - 9 are described.