76803-91-3Relevant articles and documents
Lewis Acid Promoted Decomposition of Unsaturated α-Diazo Ketones. 2. A New Initiator for Polyolefinic Cationic Cyclization
Smith, Amos B.,Dieter, R. Karl
, p. 2009 - 2016 (2007/10/02)
This report documents the first utilization of the unsaturated diazo ketone functionality in the initiation of polyolefinic cationic cyclizations.Specifically, β,γ-unsaturated diazo ketones 1 and 2 undergo a stereoselective Lewis acid promoted cyclization