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7687-02-7

2-Benzyloxy-3-methoxy-9,10-(methylenedioxy)-5,6-dihydroindolo[2,1-a]isoquinoline is a complex organic compound belonging to the class of indoloisoquinolines. This molecule features a dihydroindolo[2,1-a]isoquinoline core, which is a fused ring system consisting of an indoline and isoquinoline. The compound is characterized by the presence of a benzyloxy group at the 2-position, a methoxy group at the 3-position, and a methylenedioxy bridge connecting the 9 and 10 positions. The 5,6-dihydro part of the name indicates the presence of a double bond between carbons 5 and 6, which has been reduced to a single bond, creating a saturated ring. This chemical structure may be relevant in pharmaceutical research due to its potential biological activities, although specific applications or properties are not detailed in this summary.

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  • 7687-02-7 Structure

  • Basic information

    1. Product Name: 2-benzyloxy-3-methoxy-9,10-(methylenedioxy)-5,6-dihydroindolo[2,1-a]isoquinoline
    2. Synonyms: 2-benzyloxy-3-methoxy-9,10-(methylenedioxy)-5,6-dihydroindolo[2,1-a]isoquinoline
    3. CAS NO:7687-02-7
    4. Molecular Formula:
    5. Molecular Weight: 399.446
    6. EINECS: N/A
    7. Product Categories: N/A
    8. Mol File: 7687-02-7.mol

  • Chemical Properties

    1. Melting Point: N/A
    2. Boiling Point: N/A
    3. Flash Point: N/A
    4. Appearance: N/A
    5. Density: N/A
    6. Refractive Index: N/A
    7. Storage Temp.: N/A
    8. Solubility: N/A
    9. CAS DataBase Reference: 2-benzyloxy-3-methoxy-9,10-(methylenedioxy)-5,6-dihydroindolo[2,1-a]isoquinoline(CAS DataBase Reference)
    10. NIST Chemistry Reference: 2-benzyloxy-3-methoxy-9,10-(methylenedioxy)-5,6-dihydroindolo[2,1-a]isoquinoline(7687-02-7)
    11. EPA Substance Registry System: 2-benzyloxy-3-methoxy-9,10-(methylenedioxy)-5,6-dihydroindolo[2,1-a]isoquinoline(7687-02-7)

  • Safety Data

    1. Hazard Codes: N/A
    2. Statements: N/A
    3. Safety Statements: N/A
    4. WGK Germany:
    5. RTECS:
    6. HazardClass: N/A
    7. PackingGroup: N/A
    8. Hazardous Substances Data: 7687-02-7(Hazardous Substances Data)

7687-02-7 Usage

Check Digit Verification of cas no

The CAS Registry Mumber 7687-02-7 includes 7 digits separated into 3 groups by hyphens. The first part of the number,starting from the left, has 4 digits, 7,6,8 and 7 respectively; the second part has 2 digits, 0 and 2 respectively.
Calculate Digit Verification of CAS Registry Number 7687-02:
(6*7)+(5*6)+(4*8)+(3*7)+(2*0)+(1*2)=127
127 % 10 = 7
So 7687-02-7 is a valid CAS Registry Number.

7687-02-7Relevant articles and documents

A facile route to indolo[2,1-a]isoquinolines and dibenzopyrrocoline alkaloids

Orito, Kazuhiko,Harada, Rika,Uchiito, Shiho,Tokuda, Masao

, p. 1799 - 1801 (2000)

(Formula presented) Treatment of 1-(2′-bromobenzyl)-3,4-dihydroisoquinolines 2 in the presence of K2CO3 in boiling DMF efficiently provided a variety of alkoxysubstituted indolo[2,1-a]isoquinolines 3. Application of this cyclization

Phosphane-free Pd0-catalyzed cycloamination and carbonylation with Pd(OAc)2 and Cu(OAc)2 in the presence of K 2CO3: Preparation of benzocyclic amines and benzolactams

Harada, Rika,Nishida, Naoto,Uchiito, Shiho,Onozaki, Yu,Kurono, Nobuhito,Senboku, Hisanori,Masao, Tokuda,Ohkuma, Takeshi,Orito, Kazuhiko

, p. 366 - 379 (2012/02/04)

Phosphane-free Pd0-catalyzed intramolecular aromatic amination was studied. o-Halophenethylamines and 3-(o-halophenyl)propylamines were found to be transformed into indolines and quinolines in a catalytic system based on Pd(OAc)2 and Cu(OAc)2 in the presence of K 2CO3. Application of the method to substrates containing isoquinoline rings- the 1-(o-bromobenzyl)-3,4-dihydroisoquinolines 6, the 1-(o-bromobenzyl)-1,2,3,4-tetrahydroisoquinolines 7, and the 1-(o-bromophenethyl)isoquinolines 9- provided the indolo[2,1-a]isoquinoline and dibenzo[a,f]quinolizine ring systems 8 and 10. Extension of the method to β-carbolines (compounds 11, 12, and 17) produced the benz[f]indolo[2,3-a] indolizine-13-ones 15 and the benz[f]indolo[2,3-a]quinolizine 18. The benzo[f]pyrido[3,4-a]indolizine and indolo[f]pyrido[3,4-a]indolizin-12-one ring systems 27 and 31 were built in a similar manner. It was also found that under an atmosphere of CO the same catalytic system produced the corresponding benzolactams, the isoquino[2,1-a][2,7]naphthyridine 34 and the indolo[2,3-a]pyrido[g]quinolizin-8-one 36 [(±)-dihydronauclefine] in good yields. Copyright

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