7688-03-1Relevant articles and documents
Aromatic Metamorphosis of Thiophenes by Means of Desulfurative Dilithiation
Kaga, Atsushi,Iida, Hirokazu,Tsuchiya, Shun,Saito, Hayate,Nakano, Koji,Yorimitsu, Hideki
supporting information, p. 4567 - 4572 (2021/02/12)
A new mode of aromatic metamorphosis has been developed, which allows thiophenes and their benzo-fused derivatives to be converted to a variety of exotic heteroles. This transformation involves 1) the efficient generation of key 1,4-dianions by means of desulfurative dilithiation with lithium powder and 2) the subsequent trapping of the dianions with heteroatom electrophiles in a one-pot manner. Via the desulfurative dilithiation, the sulfur atoms of thiophenes are replaced also with a carbon–carbon double bond or a 1,2-phenylene for the construction of benzene rings.
Electron-transfer reaction of 1,2-disila-3,5-cyclohexadienes
Kako, Masahiro,Takada, Hideki,Nakadaira, Yasuhiro
, p. 3525 - 3528 (2007/10/03)
Phololysis of 1,2-disila-3,5-cyclohaxadienes 1a-b in the presence of methylene blue as a sensitizer led to efficient formation of the correspondng siloles as ring contraction products. The reaction mechanism is best rationalized by electron-transfer from