76900-60-2

Upstream product

• 16800-46-7 trisacetonitrile(tricarbonyl)chromium⁽⁰⁾ 
• 28275-94-7 1-Methyl-3,5-diphenyl-2H-thinium-tetrafluoroborat 

Downstream Products

• 82782-95-4 anti-Tricarbonyl[3,5-diphenyl-1-(2-phenylethyl)-.lamda.⁽⁴⁾-thiabenzol]tricarbonylchrom⁽⁰⁾ 
• 82782-97-6 anti-Tricarbonyl[3,5-diphenyl-1-[(trimethylgermyl)methyl]-.lamda.⁽⁴⁾-thiabenzol]chrom⁽⁰⁾ 
• 82782-96-5 anti-Tricarbonyl[3,5-diphenyl-1-[(trimethylsilyl)methyl]-.lamda.⁽⁴⁾-thiabenzol]chrom⁽⁰⁾ 
• 82782-94-3 anti-[1-(3-Butenyl)-3,5-diphenyl-.lamda.⁽⁴⁾-thiabenzol]tricarbonylchrom⁽⁰⁾ 
• 82796-19-8 anti-Tricarbonyl(1-ethyl-3,5-diphenyl-.lamda.⁽⁴⁾-thiabenzol)chrom⁽⁰⁾ 

Relevant academic research and scientific papers

Transition Metal Sulfur Ylide Complexes, XIII. ?-Complexes of 1-Alkyl-3,5-diphenyl-λ4-thiabenzene with Tricarbonylchromium, -molybdenum, and tungsten

Thermolabile 1-methyl- and 1-ethyl-3,5-diphenyl-λ4-thiabenzenes (1a,b) are trapped by tricarbonylchromium, -molybdenum, and -tungsten and stabilized by the transition metal (3a,b - 5a,b).The X-ray analysis of the chromium complex 3a shows that the complexed ligand is non-planar.No bonding interactions exist between the metal and the sulfur atom.The S-methyl group of the coordinated heterocycle is metalated by tert-butyllithium.The obtained organolithium compounds 3c, 4c, 5c are alkylated, silylated or germylated, resp., by electrophiles such as CH3I, C3H5Br, PhCH2Br, Me3SiCl, and Me3GeCl.