76911-96-1Relevant academic research and scientific papers
Oxidations catalysed by rhenium(V) oxides 2. Clean sulfide oxidation by urea-hydrogen peroxide
Gunaratne, H. Q. Nimal,McKervey, M. Anthony,Feutren, Stephanie,Finlay, James,Boyd, John
, p. 5655 - 5658 (1998)
Three rhenium(V) oxo phosphine complexes and methyltrioxorhenium have been used as catalysts for oxidation of sulfides to sulfoxides with urea- hydrogen peroxide as oxidant in acetonitrile; partial enantioselective oxidation of methylphenyl sulfide was ob
Synthesis of α-fluorinated-α,α-difunctionalized sulfides and sulfones
Jouen,Lasne,Pommelet
, p. 2413 - 2416 (2007/10/03)
The highly functionalized organofluorine compounds 3a-c were prepared from the activated dichlorinated sulfides 2a-c by displacement of a chlorine atom using nucleophilic fluorination agents such as dihydrogenfluoride polymer-supported. Fluorination of sulfoxides 5a-c with diethylaminosulfur trifluoride gives monofluoro sulfides 6a-c, subsequently transformed into α-chloro-α-fluoro sulfides 3a-c and sulfones 7a-c.
