76924-22-6Relevant academic research and scientific papers
HYDROLYSIS OF CARBAMATES AND CARBONATES OF 3-HYDROXYTHIOLANE 1,1-DIOXIDE
Parkhomenko, P. I.,Rybakova, M. V.,Bezmenova, T. E.,Zaika, T. D.
, p. 1122 - 1124 (1980)
Alkylcarbamates of 3-hydroxy-thiolane 1,1-dioxide are hydrolyzed in the presence of bases to give alkyl(1,1-dioxo-3-thiolanyl)amines and 2-thiolene 1,1-dioxide (I).Aryl esters undergo hydrolysis to give sulfone I and 3-hydroxythiolane 1,1-dioxide (II).The corresponding alkyl- and arylcarbonates also form sulfone I and a very small amount of hydroxy derivative II under these conditions.
