HYDROLYSIS OF CARBAMATES AND CARBONATES OF 3-HYDROXYTHIOLANE 1,1-DIOXIDE

DOI: 10.1007/BF00504106

Source and publish data:

Chemistry of Heterocyclic Compounds p. 1122 - 1124 (1980)

Update date:2022-08-06

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Authors:

Parkhomenko, P. I.

Rybakova, M. V.

Bezmenova, T. E.

Zaika, T. D.

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Article abstract of DOI:10.1007/BF00504106

Alkylcarbamates of 3-hydroxy-thiolane 1,1-dioxide are hydrolyzed in the presence of bases to give alkyl(1,1-dioxo-3-thiolanyl)amines and 2-thiolene 1,1-dioxide (I).Aryl esters undergo hydrolysis to give sulfone I and 3-hydroxythiolane 1,1-dioxide (II).The corresponding alkyl- and arylcarbonates also form sulfone I and a very small amount of hydroxy derivative II under these conditions.

Full text of DOI:10.1007/BF00504106

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