Chemistry of Heterocyclic Compounds p. 1122 - 1124 (1980)
Update date:2022-08-06
Topics:
Parkhomenko, P. I.
Rybakova, M. V.
Bezmenova, T. E.
Zaika, T. D.
Alkylcarbamates of 3-hydroxy-thiolane 1,1-dioxide are hydrolyzed in the presence of bases to give alkyl(1,1-dioxo-3-thiolanyl)amines and 2-thiolene 1,1-dioxide (I).Aryl esters undergo hydrolysis to give sulfone I and 3-hydroxythiolane 1,1-dioxide (II).The corresponding alkyl- and arylcarbonates also form sulfone I and a very small amount of hydroxy derivative II under these conditions.
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