76934-70-8

Upstream product

• 76934-58-2 2-(3,4-Dimethoxy-benzoyl)-3-(3,4-dimethoxy-phenyl)-cyclopropanecarboxylic acid ethyl ester 
• 75-11-6 diiodomethane 
• 4687-37-0 ethyl 3,4-dimethoxybenzoylacetate 
• 120-14-9 3,4-dimethoxy-benzaldehyde 
• 76934-58-2 ethyl 2-(3,4-dimethoxybenzoyl)-3-(3,4-dimethoxyphenyl)cyclopropane-1-carboxylate 

Relevant academic research and scientific papers

Tandem chain extension-aldol reaction: syn selectivity with a zinc enolate.

A tandem chain extension-aldol reaction was developed in which beta-keto esters are transformed to alpha-substituted-gamma-keto esters in an efficient zinc-mediated, one-pot reaction. The diastereoselectivity of the reaction ranged from good to excellent

Lewis Acid-catalysed Reactions of Aryl Cyclopropyl Ketones. Scope and Mechanism

The effects of aryl substituents on the stannic chloride-catalysed cyclisation of aryl cyclopropyl ketones (1) to aryl tetralones (2) are consistent with the formation of a benzyl carbocation intermediate (8) or a cyclic oxonium ion intermediate (12).The

TRAPPING THE INTERMEDIATE INVOLVED IN THE INTRAMOLECULAR CYCLISATION OF CYCLOPROPYL KETONES. A CONVENIENT PREPARATION OF OPEN-CHAIN γ-HYDROXY KETONES.

The concerted mechanism for the stannic chloride catalysed cyclisation of aryl cyclopropyl ketones is disproved by trapping the intermediate.The reaction provides a facile route to γ-hydroxyketones.