76943-18-5

Usage

Uses

Used in Pharmaceutical Industry:
[(2,2,2-trifluoroethoxy)sulfanyl]benzene is used as a precursor in the synthesis of pharmaceutical compounds due to its unique chemical structure, which can be manipulated to create a variety of medicinally relevant molecules.
Used in Agrochemical Industry:
In the agrochemical industry, [(2,2,2-trifluoroethoxy)sulfanyl]benzene is utilized as a starting material for the development of new pesticides and other agricultural chemicals, taking advantage of its reactive functional groups.
Used in Materials Science:
[(2,2,2-trifluoroethoxy)sulfanyl]benzene is employed as a component in the creation of advanced materials, such as polymers and coatings, due to its potential to enhance properties like durability and chemical resistance.
Used as a Solvent:
[(2,2,2-trifluoroethoxy)sulfanyl]benzene is also used as a solvent in various chemical reactions, providing a suitable medium for the reactants to mix and interact, facilitating the desired chemical transformations.
Precaution:
It is important to handle [(2,2,2-trifluoroethoxy)sulfanyl]benzene with care, as it may pose hazards if not properly used and stored. Safety measures should be taken to minimize risks during its application in different industries.

Upstream product

• 882-33-7 diphenyldisulfane 
• 75-89-8 2,2,2-trifluoroethanol 
• 931-59-9 benzenesulfenyl chloride 

Downstream Products

• 71181-76-5 pentakis(2,2,2-trifluoroethoxy)phosphorane 
• 76943-20-9 thiophenyltetrakis(2,2,2-trifluoroethoxy)phosphorane 
• 63325-06-4 phenyltetrakis(2,2,2-trifluoroethoxy)phosphorane 
• 76943-21-0 diphenyltris(2,2,2-trifluoroethoxy)phosphorane 
• 16599-17-0 2,2'-diphenyl-1,1'-ethane-1,2-diyl-bis-disulfane 
• 67696-25-7 bis(2,2,2-trifluoroethoxy)triphenylphosphorane 

Relevant academic research and scientific papers

The kinetics and mechanism of the reaction of tricoordinate phosphorus compounds with sulfenate esters

The kinetics and mechanism of the reaction of tricoordinate phosphorus compounds, ArnP(OCH2CF3)3-n with arylsulfenate esters, ArSOCH2CF3, are reported. Product analysis, kinetic order, activation parameters, Hammett data and solvent effects are the criteria used to elucidate the two step mechanism involving arylthiophosphoranes as intermediates.

THE THERMOLYTIC DECOMPOSITION OF ACYCLIC PHOSPHORANES

The thermolytic decomposition of acyclic phosphoranes, ArnP(OCH2CF3)5-n in aprotic media has been shown by kinetic studies to proceed via rate-limiting ionization of the phosphoranes.Activation parameters, deuterium isotope effects, solvent effects and ρ-values (for n = 3 and n = 1) support this concept which is consistent with the observed rate-sequence of n = 3> n = 2 > n = 1 > n = 0.Key words: Phosphoranes, thermolysis, kinetics, mechanism.

INHIBITION OF PSEUDOROTATION IN SOME MONOCYCLIC PENTAOXYPHOSPHORANES

Phosphoranes were prepared by allowing 2,4,8,10-tetra-tert-butyl-6-(2,2,2-trifluoroethoxy)-12H-dibenzodioxaphosphocin, the analogous ethoxy compound, 2,4,8,10-tetra-tert-butyl-6-(2,2,2-trifluoroethoxy)-dibenzodioxaphosphepin and the analogous compound without tert-butyl groups to react with trifluoroethyl benzenesulfonate.The first three phosphoranes showed significant barriers to intramolecular ligand reorganization, 14-16 kcal/mole.The phosphorane without the tert-butyl groups had a barrier too low to measure.These observations are discussed in terms of steric inhibition of pseudorotation.