76953-99-6

Upstream product

• 36229-42-2 (3-chlorophenyl)magnesium bromide 
• 69843-11-4 1-chloro-3-(3,3,3-trifluoroprop-1-en-2-yl)benzene 
• 421-50-1 1,1,1-trifluoro-2-propanone 
• 108-37-2 1-bromo-3-chlorobenzene 
• 917-64-6 methyl magnesium iodide 
• 321-31-3 1-(3-chlorophenyl)-2,2,2-trifluoroethanone 

Downstream Products

• 69843-11-4 1-chloro-3-(3,3,3-trifluoroprop-1-en-2-yl)benzene 
• 122243-12-3 3-Nitro-benzenesulfonic acid 1-(3-chloro-phenyl)-2,2,2-trifluoro-1-methyl-ethyl ester 
• 76954-02-4 1-(3-chlorophenyl)-1-(trifluoromethyl)ethyl tosylate 

Relevant academic research and scientific papers

Solvolytic Studies of the Highly Deactivated 1-Aryl-1-(trifluoromethyl)ethyl Tosylates

The rates of solvolysis of 1-aryl-1-(trifluoromethyl)ethyl tosylates 1b-i and 1-aryl-1-(trifluoromethyl)ethyl bromides 3a,b in 80percent ethanol, and of 1-phenyl- and 1-(3-chlorophenyl)-1-(trifluoromethyl)ethyl tosylates (1e and 1g) in a variety of solven

SOLVOLYSIS OF 1-ARYL-1-(TRIFLUOROMETHYL)ETHYL TOSYLATES. EVIDENCE FOR AN EXTREMELY HIGH ELECTRON DEMAND CARBENIUM ION INTERMEDIATE DUE TO THE PRESENCE OF α-TRIFLUOROMETHYL SUBSTITUENT

The rate-retarding effect of α-trifluoromethyl group observed in the solvolysis of 1-aryl-1-(trifluoromethyl)ethyl tosylates is so profound that a very large negative ρ+ value, -8.82, is resulted and the 1-phenyl derivative becomes even less re