76954-01-3Relevant academic research and scientific papers
Solvolytic Studies of the Highly Deactivated 1-Aryl-1-(trifluoromethyl)ethyl Tosylates
Liu, Kwang-Ting,Kuo, Mann-Yan,Shu, Ching-Fen
, p. 211 - 215 (2007/10/02)
The rates of solvolysis of 1-aryl-1-(trifluoromethyl)ethyl tosylates 1b-i and 1-aryl-1-(trifluoromethyl)ethyl bromides 3a,b in 80percent ethanol, and of 1-phenyl- and 1-(3-chlorophenyl)-1-(trifluoromethyl)ethyl tosylates (1e and 1g) in a variety of solven
SOLVOLYSIS OF 1-ARYL-1-(TRIFLUOROMETHYL)ETHYL TOSYLATES. EVIDENCE FOR AN EXTREMELY HIGH ELECTRON DEMAND CARBENIUM ION INTERMEDIATE DUE TO THE PRESENCE OF α-TRIFLUOROMETHYL SUBSTITUENT
Liu, Kwang-Ting,Sheu, Ching-Fen
, p. 4091 - 4094 (2007/10/02)
The rate-retarding effect of α-trifluoromethyl group observed in the solvolysis of 1-aryl-1-(trifluoromethyl)ethyl tosylates is so profound that a very large negative ρ+ value, -8.82, is resulted and the 1-phenyl derivative becomes even less re
