76966-26-2Relevant academic research and scientific papers
ACTION DES DIALKYLCUPRATES DE LITHIUM SUR LES ALDEHYDES α,β-ETHYLENIQUES
Chuit, C.,Foulon, J. P.,Normant, J. F.
, p. 2305 - 2310 (2007/10/02)
Nearly exclusive 1-4 addition products are obtained by action of lithium dialkylcuprates with α,β-ethylenic aldehydes.Non polar solvents and low temperatures favor this reaction.Only α,β-ethylenic aldehydes having a trisubstituted double bond give a relatively important proportion of 1-2 addition product.
