769929-27-3Relevant academic research and scientific papers
Silver Salt-Mediated Allylation Reactions Using Allyl Bromides
Xiong, Xiaodong,Wong, Jonathan,Yeung, Ying-Yeung
supporting information, p. 6974 - 6982 (2021/05/06)
A facile, efficient, and chemoselective synthesis of allylic amides has been developed. Allyl bromides were used as the precursors activated by silver triflate. A Ritter-type reaction readily proceeded to give various allyl amides under mild conditions. The reaction protocol was also applicable to different nucleophilic partners to give a wide range of allyl-substituted products in the absence of a base.
Efficient and convenient C-3 functionalization of indoles through Ce(OAc)3/TBHP-mediated oxidative C-H bond activation in the presence of β-cyclodextrin
Hu, Yu Lin,Jiang, Hui,Lu, Ming
experimental part, p. 3079 - 3087 (2011/12/15)
A simple, green and efficient protocol for the selective C-3 functionalization of indoles with ketones and olefins via Ce(OAc) 3-TBHP mediated oxidative C-H activation in the presence of β-cyclodextrin in water has been developed. This atom-eco
Electrophilic allylations and benzylations of indoles in neutral aqueous or alcoholic solutions
Westermaier, Martin,Mayr, Herbert
, p. 4791 - 4794 (2007/10/03)
(Chemical Equation Presented) Indoles are allylated and benzylated in moderate to quantitative yield when stirred with allyl and benzyl halides in 80% aqueous acetone in the presence of NH4HCO3 at room temperature.
New versatile Pd-catalyzed alkylation of indoles via nucleophilic allylic substitution: Controlling the regioselectivity
Bandini, Marco,Melloni, Alfonso,Umani-Ronchi, Achille
, p. 3199 - 3202 (2007/10/03)
(Chemical Equation Presented) A systematic study addressed toward the optimization of the Pd-catalyzed alkylation of indoles by allylic carbonates is presented. The protocol uses a catalytic amount of [PdCl(π-allyl)] 2/phosphine as a promoting
