77003-39-5

Upstream product

• 100-11-8 1-bromomethyl-4-nitro-benzene 
• 77003-38-4 (3RS,4RS)-4-allyl-3-ethylazetidin-2-one 
• 603-35-0 triphenylphosphine 

Downstream Products

• 77003-41-9 (2RS,3SR,5SR,6SR)-p-nitrobenzyl 3-(2-acetamidoethylthio)-6-ethyl-7-oxo-1-azabicyclo<3.2.0>heptane-2-carboxylate 
• 77003-41-9 (2RS,3RS,5SR,6SR)-p-nitrobenzyl 3-(2-acetamidoethylthio)-6-ethyl-7-oxo-1-azabicyclo<3.2.0>heptane-2-carboxylate 
• 77003-41-9 (2RS,3RS,5RS,6RS)-p-nitrobenzyl 3-(2-acetamidoethylthio)-6-ethyl-7-oxo-1-azabicyclo<3.2.0>heptane-2-carboxylate 

Relevant academic research and scientific papers

Olivanic Acid Analogues. Part 6. Biomimetic Synthesis of (+/-)-PS-5, (+/-)-6-Epi-PS-5, and (+/-)-Benzyl MM22381

Michael addition of thiols to 6-substituted azabicyclohept-2-ene-2-carboxylates, followed by reintroduction of the double bond with iodobenzene dichloride-pyridine under anhydrous conditions, provides a biomimetic strategy for the synthesis of 3-al