77003-41-9

Upstream product

• 1190-73-4 2-(acetylamino)ethanethiol 
• 77003-40-8 (5RS,6RS)-p-nitrobenzyl 6-ethyl-7-oxo-1-azabicyclo<3.2.0>hept-2-ene-2-carboxylate 
• 77003-47-5 (2RS,3SR,5SR,6RS)-p-nitrobenzyl 3-(2-acetamidoethylthio)-6-(2-methylsulphonyloxyethyl)-7-oxo-1-azabicyclo<3.2.0>heptane-2-carboxylate 
• 77003-47-5 (2S,5R,6S)-3-(2-Acetylamino-ethylsulfanyl)-6-(2-methanesulfonyloxy-ethyl)-7-oxo-1-aza-bicyclo[3.2.0]heptane-2-carboxylic acid 4-nitro-benzyl ester 
• 100-11-8 1-bromomethyl-4-nitro-benzene 
• 77003-39-5 (3RS,4RS)-p-nitrobenzyl <4-allyl-3-ethyl-2-oxoazetidin-1-yl>(triphenylphosphoranylidene)acetate 
• 77003-38-4 (3RS,4RS)-4-allyl-3-ethylazetidin-2-one 
• 77003-41-9 (2RS,3RS,5RS,6RS)-p-nitrobenzyl 3-(2-acetamidoethylthio)-6-ethyl-7-oxo-1-azabicyclo<3.2.0>heptane-2-carboxylate 

Downstream Products

• 77003-42-0 (2RS,5RS,6SR)-p-nitrobenzyl 3-(2-acetamidoethylthio)-6-ethyl-7-oxo-1-azabicyclo<3.2.0>hept-3-ene-2-carboxylate 
• 130711-95-4 (2RS,5RS,6RS)-p-nitrobenzyl 3-(2-acetamidoethylthio)-4-chloro-6-ethyl-7-oxo-1-azabicyclo<3.2.0>hept-3-ene-2-carboxylate 
• 77003-42-0 (2RS,5RS,6RS)-p-nitrobenzyl 3-(2-acetamidoethylthio)-6-ethyl-7-oxo-1-azabicyclo<3.2.0>hept-3-ene-2-carboxylate 
• 77003-41-9 (2RS,3SR,5SR,6SR)-p-nitrobenzyl 3-(2-acetamidoethylthio)-6-ethyl-7-oxo-1-azabicyclo<3.2.0>heptane-2-carboxylate 
• 71730-34-2 cis-(+/-)-3-<<2-(acetylamino)ethyl>thio>-6-ethyl-7-oxo-1-azabicyclo<3.2.0>hept-2-ene-2-carboxylic acid <(4-nitrophenyl)methyl> ester 
• 71730-34-2 (5RS,6RS)-p-nitrobenzyl 3-(2-acetamidoethylthio)-6-ethyl-7-oxo-1-azabicyclo<3.2.0>hept-2-ene-2-carboxylate 

Relevant academic research and scientific papers

Olivanic Acid Analogues. Part 6. Biomimetic Synthesis of (+/-)-PS-5, (+/-)-6-Epi-PS-5, and (+/-)-Benzyl MM22381

Michael addition of thiols to 6-substituted azabicyclohept-2-ene-2-carboxylates, followed by reintroduction of the double bond with iodobenzene dichloride-pyridine under anhydrous conditions, provides a biomimetic strategy for the synthesis of 3-al

Olivanic Acids and Related Compounds: Total Synthesis of (+/-)-PS-5 and (+/-)-6-Epi PS-5

The trans- and cis-substituted β-lactam isomers of p-nitrobenzyl 3-(2-acetamidoethylthio)-6-ethyl-7-oxo-1-azabicycloheptane-2-carboxylate can be oxidised with iodobenzene dichloride-pyridine under anhydrous conditions to give the 3,4-unsaturated es