77003-54-4

Basic information

• Product Name: (3R,4R,5R)-3-benzoyloxy-4,5-dihydroxycyclohexanone 4,5-O-cyclohexylidene acetal
• Synonyms: (3R,4R,5R)-3-benzoyloxy-4,5-dihydroxycyclohexanone 4,5-O-cyclohexylidene acetal
• CAS NO: 77003-54-4
• Molecular Weight: 330.381
• Mol File: 77003-54-4.mol
• Article Data: 4

Chemical Properties

• CAS DataBase Reference: (3R,4R,5R)-3-benzoyloxy-4,5-dihydroxycyclohexanone 4,5-O-cyclohexylidene acetal(CAS DataBase Reference)
• NIST Chemistry Reference: (3R,4R,5R)-3-benzoyloxy-4,5-dihydroxycyclohexanone 4,5-O-cyclohexylidene acetal(77003-54-4)
• EPA Substance Registry System: (3R,4R,5R)-3-benzoyloxy-4,5-dihydroxycyclohexanone 4,5-O-cyclohexylidene acetal(77003-54-4)

Safety Data

• Hazardous Substances Data: 77003-54-4(Hazardous Substances Data)

Upstream product

• 53397-93-6 3-O,4-O-cyclohexylidene-(3R,4S,5R)-trihydroxycyclohexan-1-one 
• 98-88-4 benzoyl chloride 
• 35949-54-3 (1R,2S,3R,5R)-1,2-O-cyclohexylidene-5-C-(hydroxymethyl)-1,2,3,5-cyclohexanetetrol 
• 108-94-1 cyclohexanone 
• 35949-53-2 (-)-4,5-cyclohexylidenequinic acid lactone 
• 77-95-2 D-(-)-quinic acid 

Downstream Products

• 83182-00-7 (2R)-1-benzoyloxy-5-(5,5-dimethyl-1,3-dioxan-2-yl)-2-methanesulphonyloxypentan-4-one ethylene dithioacetal 
• 83181-96-8 (2R)-1-benzoyloxy-2-methanesulfonyloxy-6-(t-butyldimethylsiloxy)hexan-4-one ethylene dithioacetal 
• 83181-99-1 (2R)-1-benzoyloxy-5-formyl-2-methylsulphonyloxypentan-4-one ethylene dithioacetal 
• 83181-95-7 (2R)-1-benzoyloxy-2-hydroxy-6-(t-butyldimethylsilyloxy)-hexan-4-one ethylene dithioacetal 
• 83181-97-9 (2R)-1-benzoyloxy-6-hydroxy-2-methanesulfonyloxyhexan-4-one ethylene dithioacetal 
• 77003-58-8 (2R)-1-benzoyloxy-2,6-dihydroxyhexan-4-one ethylene dithioacetal 
• 77003-63-5 (2R)-1-benzoyloxy-2-carbamoyloxy-7,9-dioxadecan-4-one ethylene dithioacetal 
• 77003-60-2 (2R)-1-benzoyloxy-2-hydroxy-7,9-dioxadecan-4-one ethylene dithioacetal 
• 77003-57-7 (5R)-5-benzoyloxy-1,6-dihydroxy-3-hexanone ethylene dithioacetal 
• 77003-55-5 (7R,8R,9R)-9-benzoyloxy-7,8-dihydroxy-1,4-dithiaspiro<4.5>decane 
• 13427-53-7 4-(2-hydroxyethoxy)-phenol 
• 88341-44-0 (7R,8R,9R)-9-benzoyloxy-7,8-dihydroxy-1,4-dioxaspiro<4.5>decane 
• 88341-43-9 (7R,8R,9R)-9-benzoyloxy-7,8-O-cyclohexylidene-7,8-dihydroxy-1,4-dioxaspiro<4.5>decane 

Relevant articles and documents

Studies Related to Maytansinoids

A rapid and high yielding route to optically active β-carbamoyloxy ketones of use in the synthesis of maytansinoids has been devised, starting from quinic acid.

Synthesis of Enantiomerically Pure Substituted Cyclopentenes from (-)-Quinic Acid

The synthesis of a large variety of enantiomerically pure substituted reactive cyclopentenes 16, 23, 24 and 28 have been synthesized from the readily available (-)-quinic acid 1.The straightforward strategy involves a high-yielding intramolecular aldoliza