77008-37-8

Basic information

• Product Name: 2-((2-Hydroxy-phenyl)-{[1-(2-hydroxy-phenyl)-meth-(E)-ylidene]-amino}-methyl)-malonic acid dimethyl ester
• Synonyms: 2-((2-Hydroxy-phenyl)-{[1-(2-hydroxy-phenyl)-meth-(E)-ylidene]-amino}-methyl)-malonic acid dimethyl ester
• CAS NO: 77008-37-8
• Molecular Weight: 357.363
• Mol File: 77008-37-8.mol
• Article Data: 2

Chemical Properties

• CAS DataBase Reference: 2-((2-Hydroxy-phenyl)-{[1-(2-hydroxy-phenyl)-meth-(E)-ylidene]-amino}-methyl)-malonic acid dimethyl ester(CAS DataBase Reference)
• NIST Chemistry Reference: 2-((2-Hydroxy-phenyl)-{[1-(2-hydroxy-phenyl)-meth-(E)-ylidene]-amino}-methyl)-malonic acid dimethyl ester(77008-37-8)
• EPA Substance Registry System: 2-((2-Hydroxy-phenyl)-{[1-(2-hydroxy-phenyl)-meth-(E)-ylidene]-amino}-methyl)-malonic acid dimethyl ester(77008-37-8)

Safety Data

• Hazardous Substances Data: 77008-37-8(Hazardous Substances Data)

Upstream product

• 90-02-8 salicylaldehyde 
• 108-59-8 malonic acid dimethyl ester 
• 35832-40-7 N,N'-Bis<2-hydroxybenzylidene>-2-hydroxyphenylmethanediamine 

Relevant articles and documents

Preparation of cyclic boramides from salicylaldehydes, ammonium acetate and sodium borohydride

Borohydride reduction of salicylaldehyde imines yields surprisingly a cyclic boramide. This is a fairly stable compound, and X-ray analysis shows it has a tetrahedral boron atom. Mechanistic studies show a reaction pathway through an oxazaborinane intermediate. The reaction also works with halogen substituted salicylaldehydes and for the preparation of non-symmetrical boramides.