7706-85-6Relevant academic research and scientific papers
Total syntheses of all the amathaspiramides
Chiyoda, Koji,Shimokawa, Jun,Fukuyama, Tohru
supporting information; experimental part, p. 2505 - 2508 (2012/04/18)
Six in one blow: Total syntheses of all the amathaspiramide alkaloids have been accomplished. Rapid construction of the diazaspiro[3.3]nonane core combined with regio- and diastereoselective reduction of the cyclic imide moiety with DIBAL established the route to the common structural motif. The late-stage reduction of the lactam to an imine functionality mediated by Schwartz's reagent was the key to the streamlined syntheses. Copyright
An expedient palladium-mediated route to 3-arylfurans
Taniguchi, Takahiko,Nagata, Hiroshi,Kanada, Regina Mikie,Kadota, Kohei,Takeuchi, Miwako,Ogasawara, Kunio
, p. 67 - 71 (2007/10/03)
A facile route to 3-arylfurans has been developed by employing the Heck reaction between 2,5-dihydro-2,5-dimethoxyfuran and aryl iodides as the key step.
