77063-33-3Relevant academic research and scientific papers
Preparation and Reaction of 1-(Methylthio- and phenylthio)vinyllithium Reagents
Takeda, Takeshi,Furukawa, Hiroyuki,Fujimori, Mizue,Suzuki, Kouichi,Fujiwara, Tooru
, p. 1863 - 1869 (2007/10/02)
An improved procedure for the preparation of 1-(methylthio- and phenylthio)vinyllithium reagents utilizing 2-methoxyalkyl sulfides was developed and their reactions with ketones, aldehydes, oxiranes, and alkyl halides were studied.
HIGHLY STEREOSELECTIVE SYNTHESIS OF TRISUBSTITUTED OLEFINS FROM ALKENYL ARYL SULFOXIDES
Takei, Hisashi,Sugimura, Hideyuki,Miura, Morikazu,Okamura, Hisashi
, p. 1209 - 1212 (2007/10/02)
Alkenyl aryl sulfoxides could be alkylated stereoselectively via their lithium salts to afford α-alkylated (E)-alkenyl sulfoxides.Reduction of the sulfoxides to the corresponding sulfides followed by nickel-phosphine complexes catalyzed coupling reaction
