93242-22-9

Upstream product

• 104-53-0 3-phenyl-propionaldehyde 
• 100-68-5 methyl-phenyl-thioether 
• 1126-76-7 1,2-Epoxy-4-phenylbutane 
• 930-69-8 sodium thiophenolate 
• 768-56-9 4-Phenylbut-1-ene 
• 17873-08-4 (phenylsulfanylmethyl)trimethylsilane 

Downstream Products

• 93242-24-1 2-methoxy-4-phenylbutyl phenyl sulfide 
• 23853-68-1 phenyl(1,2,3,4-tetrahydronaphthalen-2-yl)sulfane 
• 77063-33-3 5-phenyl-2-phenylthio-2-pentene 
• 93242-58-1 1-phenyl-4-phenylthio-3-dodecene 
• 93242-33-2 4-phenyl-1-phenylthio-1-bytenyllithium 
• 67004-76-6 phenyl(4-phenylbut-1-enyl)sulfane 
• 82561-86-2 (1E,4Z)-1,7-Diphenyl-4-phenylsulfanyl-hepta-1,4-dien-3-ol 
• 82561-90-8 (Z)-7-Phenyl-4-phenylsulfanyl-hept-4-en-3-ol 
• 82561-92-0 (Z)-2-Methyl-8-phenyl-5-phenylsulfanyl-oct-5-en-4-ol 
• 82561-84-0 (Z)-1,5-Diphenyl-2-phenylsulfanyl-pent-2-en-1-ol 
• 82561-88-4 (Z)-1,7-Diphenyl-4-phenylsulfanyl-hept-4-en-3-ol 

Relevant academic research and scientific papers

Highly stereoselective Friedel-Crafts alkylations of unactivated benzenes by episulfonium ion cyclizations

Intermolecular additions of highly enantiomerically enriched episulfonium ions onto activated benzene rings are known to accomplish chiral Friedel-Crafts alkylations. Unactivated benzenes are either unreactive or can give low stereoselectivities. Intramol

NOVEL ARYLTHIOMETHYLATION OF CARBONYL COMPOUNDS USING ARYLTHIOMETHYLTRIMETHYLSILANES CATALYZED BY FLUORIDE IONS. NEW ROUTE TO β-HYDROXYARYLSULFIDES

Arylthiomethyltrimethylsilanes are good and mild nucleophilic reagents for introducing arylthiomethyl groups into carbonyl compounds promoted by tetra-n-butylammonium fluoride to give the corresponding β-hydroxyarylsulfides in fairly good yields.

A CONVENIENT MATHOD FOR PREPARATION OF 1-(METHYLTHIO) AND 1-(PHENYLTHIO)VINYLLITHIUM REAGENTS

1-(Methylthio) and 1-(phenylthio)vinyllithiums were prepared by the treatment of the corresponding 2-methoxyethyl sulfides with twice molar amounts of butyllithium in the presence of N,N,N',N'-tetramethylethylenediamine (TMEDA). β-Alkylthio-β,γ-unsaturated alcohols were obtained in good yields by the reaction of the lithium salts with aldehydes.