77076-31-4Relevant academic research and scientific papers
Synthesis of Diamantane Derivatives in Nitric Acid Media
Klimochkin, Yu. N.,Ivleva,Zaborskaya
, p. 186 - 194 (2021/03/26)
Abstract: 1-Mono- and 1,4-difunctional diamantane derivatives were synthesized by the reaction of diamantane with nitric acid or a HNO3–AcOH mixture followed by the addition of nitrogen-containing nucleophiles. Methyl N-(diamantan-1-yl)carbamothioate was synthesized from diamantan-1-ol and methyl thiocyanate in sulfuric acid.
Hydroxy derivatives of diamantane, triamantane, and [121]tetramantane: Selective preparation of bis-apical derivatives
Fokina, Natalie A.,Tkachenko, Boryslav A.,Merz, Anika,Serafin, Michael,Dahl, Jeremy E. P.,Carlson, Robert M. K.,Fokin, Andrey A.,Schreiner, Peter R.
, p. 4738 - 4745 (2008/03/13)
Functionalizations of diamantane, triamantane, and tetramantane with electrophihc reagents (Br2, nitric acid) lead to various apical and medial disubstituted products that were separated and characterized individually. The highly desirable and otherwise inaccessible thermodynamically more stable apical bis-derivatives were obtained with high preparative yields through acid catalyzed isomerizations. Wiley-VCH Verlag GmbH & Co. KGaA, 2007.
SYNTHESIS OF DIAMANTANEDICARBOXYLIC ACIDS WITH THE CARBOXY GROUPS BONDED AT TERTIARY CARBON ATOMS
Vodicka, Ludek,Janku, Josef,Burkhard, Jiri
, p. 1162 - 1172 (2007/10/02)
The preparation of diamantanedicarboxylic acids with the carboxy groups at the tertiary carbon atoms of the diamantane skeleton is described.The procedure comprises bromination or oxidation of 1- and 4-diamantanecarboxylic acids and Koch-Haaf carboxylation of the reaction products.Of the four diamantanedicarboxylic acids synthesized, two - 1,4- and 1,7-diamantanedicarboxylic acids - have not been so far described.
