77076-31-4Relevant articles and documents
Synthesis of Diamantane Derivatives in Nitric Acid Media
Klimochkin, Yu. N.,Ivleva,Zaborskaya
, p. 186 - 194 (2021/03/26)
Abstract: 1-Mono- and 1,4-difunctional diamantane derivatives were synthesized by the reaction of diamantane with nitric acid or a HNO3–AcOH mixture followed by the addition of nitrogen-containing nucleophiles. Methyl N-(diamantan-1-yl)carbamothioate was synthesized from diamantan-1-ol and methyl thiocyanate in sulfuric acid.
SYNTHESIS OF DIAMANTANEDICARBOXYLIC ACIDS WITH THE CARBOXY GROUPS BONDED AT TERTIARY CARBON ATOMS
Vodicka, Ludek,Janku, Josef,Burkhard, Jiri
, p. 1162 - 1172 (2007/10/02)
The preparation of diamantanedicarboxylic acids with the carboxy groups at the tertiary carbon atoms of the diamantane skeleton is described.The procedure comprises bromination or oxidation of 1- and 4-diamantanecarboxylic acids and Koch-Haaf carboxylation of the reaction products.Of the four diamantanedicarboxylic acids synthesized, two - 1,4- and 1,7-diamantanedicarboxylic acids - have not been so far described.